Volkova T. V., Zherebtsov V. L., Levikhin A. A.
Abstract. Domestically, microthrusters operating based on the catalytic decomposition of a high-energy chemical compound – hydrazine (N2H4) – are used for the attitude control systems of several spacecraft (SC). Both compact briquetted metal catalysts, such as K-53, and supported catalysts, such as K-201, are used in these engines. The K-53 metal catalyst is used in thermocatalytic thrusters. However, due to the low activity of this catalyst at temperatures below 100 °C, its preheating temperature before thruster startup must be above 350 °C. This requires high power consumption aboard the spacecraft. Highly active iridium-based catalysts offer advantages in terms of activity and bed loading capacity. The K-201 catalyst is used in Russia. Like all highly active catalysts, it utilizes iridium (29–33 %) as an active component, as it is the most active metal in the hydrazine decomposition reaction. The feasibility of creating a combined catalyst that integrates the best qualities of both types is investigated. Additive manufacturing, also known as 3D printing, aids in resolving the issue of the creation and manufacturing methods of a new metal catalyst. The advent of 3D printing has opened new possibilities for manufacturing reactor parts, organizing propellant combustion processes in power systems, and creating complex internal structures of chemical reactors. The most attractive aspect of additive manufacturing is that it enables the production of parts with any desired configuration. The layer-by-layer melting of powders involves a stage of porous structure formation, which can be investigated as a support for a porous catalyst. These possibilities are explored.
Keywords: catalyst, iridium catalyst, highly porous cellular materials, metal catalysts, 3D printing, selective laser melting, additive manufacturing, new technologies
For citation: Volkova T. V., Zherebtsov V. L., Levikhin A. A. Development of a technology for manufacturing structured catalysts and rocket engine catalyst beds using 3D printing. Aerospace Engineering and Technology. 2026. Vol. 4, no. 1, pp. 75–91. (In Russ.) https://doi.org/10.52467/2949-401X-2026-4-1-75-91; https://elibrary.ru/IQUEUO
References
1. Gaydey T. P., Didyk V. A., Pimenova T. F., Zduhova T. V. Catalysts for decomposition of single-component fuels and products based on them used in engineering. Physicochemical aspects of extreme states and structural transformations in continuous media, materials and technical systems (In Russ.) https://doi.org/10.25960/7325-1150-5-46
2. Chen Z. Understanding of the Modeling Method in Additive Manufacturing. IOP Conference Series: Materials Science and Engineering, International Conference on Optoelectronic Science and Materials 20–22 September 2019, Hefei, China. 2020 Vol. 711, 7 p. https://doi.org/10.1088/1757-899X/711/1/012017
3. Bogdanova E. A., Ponomarev I. Y., Nasedkin A. V. Development and implementation of promising technologies in JSC EDB Fakel. Spacecrafts & Technologies. 2024. Vol. 47, no. 1, pp. 26–33. (In Russ.)
4. Stiles A. B. Catalyst supports and supported catalysts: theoretical and applied concepts. Boston: Butterworth-Heinemann, 1987. 270 p.
5. Proydakov E. M. The 3D printing as the new scientific and technical direction. Naukovedcheskie issledovaniya. 2014. No. 2014. 146–154. (In Russ.) https://elibrary.ru/RDOHBV
6. Kolchanov D. S., Drenin A. A., Denezhkin A. O., Shustova L. A., Safiullin S. R. Features of the Process of Selective Laser Melting from Structural Steel 28Cr3SiNiMoWV. BMSTU Journal of Mechanical Engineering. 2022. No. 10, pp. 79–88. (In Russ.) https://doi.org/10.18698/0536-1044-2022-10-97-88
7. Elistratova A. A., Korshakevich I. S., Tikhonenko D. V. 3D-printing techologies: advantages and disadvantages. 2015. № 11. С. 557-559. (In Russ.) https://elibrary.ru/VSCLQL
8. Kilina P. N., Drozdov A. A., Sirotenko L. D. Formation samples with cellular structures by selective laser sintering of metal powders. Metalworking. 2015. Vol. 87, no. 3. C. 29–31. (In Russ.)
9. Dovbysh V. M., Zabednov P. V., Zlenko M. A. Additive technologies and metal products. Bibliotechka liteischika [Foundrymans’s Library]. 2014. № 9. С. 14–71. (In Russ.)
10. Geguzin Y. E. Fizika spekaniya [Sintering physics]. Moscow: Nauka, 1984. 312 p. (In Russ.)
11. Novikov I. I., Rozin K. M. Kristallografiya i defekty kristallicheskoj reshetki [Crystallography and crystal lattice defects]. Moscow: Metallurgiya, 1990. 336 p. (In Russ.)
12. Zlenko M. A., Popovich A. A., Mutylina I. N. Additivnye tekhnologii v mashinostroenii [Additive technologies in mechanical engineering]. St. Petersburg: Polytechnic University Publ., 2013. P. 221. ISBN: 978-5-7422-4025-9. (In Russ.) https://elibrary.ru/YIMDKR
13. Froes. F. H., Smugeresky. J. E. (Eds.). Powder Metallurgу of Titanium alloys: Proceedings of a Symposium at the AIME Annual Meeting, Las Vegas, Nevada, Feb. 24–28, 1980. Warrendale, Pa.: Metallurgical Society of AIME, 1980.
14. Gordeev G. A. Modelirovanie teplofizicheskih processov v poroshkah metallov pri selektivnom lazernom plavlenii: Avtoref. dis. kand. faiz.-mat. nauk. [Modeling of thermophysical processes in metal powders during selective laser melting: Abstract of thesis of a dis. cand. Phys.-Math. Sciences]. Perm, 2020. 16 p. (In Russ.) https://elibrary.ru/YWZNYS
15. Specter Yu. E., Eromasov R. G. Tekhnologiya naneseniya i svojstva pokrytij : kurs lekcij [Coating technology and properties: course of lectures]. Krasnoyarsk, 2008. 271 pp. (In Russ.) https://elibrary.ru/YZBCTU
16. Popkova I. S., Zolotorevsky V. S., Solonin A. N. Fabrication of Products in Aluminium and its Alloys by the Selective Laser Melting Technique. Technology of light alloys. 2015. № 4. С. 14–24. (In Russ.)
17. Krivilyov M. D., Mesarovic S. D., Sekulic D. P. Phase-field model of interface migration and powder consolidation in additive manufacturing of metals. Journal of Materials Science. 2017. Vol. 52, no. 8. pp. 4155–4163. https://doi.org/10.1007/s10853-016-0311-z
18. Nikulshin P. A., Dorokhov V. S., Ovsienko O. L., Rogozina M. V., Anikeev N. A., Sidel’nikov I. V., Chugunov S. S. Computer-aided modeling and additive manufacturing of promising protective layer materials for catalytic reactors. Petroleum Chemistry. 2021. Vol. 61, no 11, pp. 1207–1216. https://doi.org/10.31857/S0028242121060058
19. Ovchinnikov A., Olshanetskiy V., Dzhugan A. Application of non-spherical hydrogenation and dehydrogenation titanium powder for obtaining products in additive technologies. Bulletin of Engine Building. 2015. No 1. Pp. 114–117. (In Russ.
